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Engineering Group Research Article 文章编号: igmin127

Kinetic Study of the Removal of Reafix Yellow B8G Dye by Boiler Ash

Industrial Engineering Materials Science DOI10.61927/igmin127 Affiliation

Affiliation

    1Departament of Chemical Engineering, Federal University of Technology-Paraná, Ponta Grossa, Paraná, Brazil

    2Alphacarbo Industrial Ltda, Guarapuava, Ponta Grossa, Paraná, Brazil

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摘要

The textile sector has great relevance in the Brazilian socioeconomic context, generating large volumes of effluents of varied composition, with dyes being one of the most worrying contaminants due to their characteristics of high solubility, harmfulness and low degradability. Among them the Reafix Yellow B8G (ARB8G) dye has an azo nature, harmful to organisms in the aquatic environment. According to Brazilian laws, it is recommended to dispose of waste through incineration or landfill, due to its resistance to biodegradation. One of the methods for treating effluents is the adsorption of contaminants using materials with adsorption capacity, such as residue from the burning of biomass in boilers (ash). The general objective of this work was to evaluate the adsorption kinetics by contact time of the ARB8G dye by boiler ash. The test was based on mixing the adsorbent material with a dye solution at 75 mg.L-1, at constant temperature and stirring at different time intervals. To quantify the amount of adsorbed dye, the UV-Vis spectrometry method was used. The kinetic test indicated an equilibrium time of 30 minutes, with 100% removal under the tested conditions. From this result and considering that boiler residue is an underutilized and low-cost material, it is concluded that this substance has significant potential to be applied as an alternative material for the treatment of effluents containing dyes.

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参考文献

    1. DESA U. The Sustainable Development Goals Report 2023: Special Edition-July 2023. New York, USA. 2023.
    2. Aigbe UO, Ukhurebor KE, Onyancha RB, Osibote OA, Darmokoesoemo H, Kusuma HS. Fly ash-based adsorbent for adsorption of heavy metals and dyes from aqueous solution: a review. Journal of Materials Research and Technology. 2021; 14:2751-2774.
    3. FISPQ nº 0222/08 of 2008. Chemical Product Safety Data Sheet: Reafix Yellow. Barueri, SP: AGS Química.
    4. Martins TMDA. Adsorption of dyes and metals and the use of waste using biosorbents: a review. 2020.
    5. Silva BCD. Biosorption of Reafix B8G Yellow dye from malt bagasse in batch and continuous system: experimental evaluation and computational fluid dynamic simulation (Master's thesis, Federal Technological University of Paraná). 2019.
    6. Hawerroth M. Granite rock powder in the removal of dye in effluent and application in Portland cement matrix (Master's thesis, Federal Technological University of Paraná). 2023.
    7. Santos J, Silva M. Adsorption of Methylene Blue Using Rice Husk. In Proceedings of the XIII COBEQ–IC 2019-Brazilian Congress of Chemical Engineering in Scientific Initiation. 2019; 19461952.
    8. Raganati F, Miccio F, Ammendola P. Adsorption of carbon dioxide for post-combustion capture: A review. energy & fuels. 2021; 35(16):12845-12868.

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